The Nigerians looked more convincing than in previous games, with Odemwingie netting either side of half-time and substitute Martins coming on to score.
Mozambique looked bright early on and were unlucky not to get on the scoresheet, with Paito threatening.
Nigeria qualify second from Group C behind Egypt, who topped the group.
The Super Eagles started a lot more positively than in their previous two matches, with John Obi Mikel just failing to find striker Yakubu Ayegbeni and Odemwingie making his first darting run forward and shooting wide early on.
On nine minutes, a poor Mozambique clearance went straight to Nigeria's Chinedu Obasi, who shot straight across goalkeeper Rafael, who covered it well and parried to safety.
The Mambas had a great opportunity minutes later, after some neat build-up play saw the ball through to winger Paito who unleashed a fierce long-range effort that breezed past the top corner.
Obasi looked in a great position mid-way through the half when Shittu headed down a dangerous ball to the striker, who snapped at the ball, giving Rafael a chance to gather.
Odemwingie again threatened when he fired off a shot at Rafael's near post that the keeper got down to well.
On nine minutes, a poor Mozambique clearance went straight to Nigeria's Chinedu Obasi, who shot straight across goalkeeper Rafael, who covered it well and parried to safety.
The Mambas had a great opportunity minutes later, after some neat build-up play saw the ball through to winger Paito who unleashed a fierce long-range effort that breezed past the top corner.
Obasi looked in a great position mid-way through the half when Shittu headed down a dangerous ball to the striker, who snapped at the ball, giving Rafael a chance to gather.
Odemwingie again threatened when he fired off a shot at Rafael's near post that the keeper got down to well.
Paito then hammered in another spectacular effort on the half hour, forcing a diving save out of Nigeria keeper Vincent Enyeama.
Nigeria went back into their shells for a spell and allowed the Mozambicans to come onto the ball, before Odemwingie took charge and created the opener single-handedly.
The Lokomotiv Moscow man was gifted acres of space and time as he ran at the Mambas' defence and gratefully picked his spot to brilliantly fire in past the diving Rafael.
It was a deserved goal for a player who had been knocking on the door throughout the half.
Nigeria doubled their lead just after the break with a clinical break from their own half.
Yakubu was played onside on the left and squared for the on-rushing Odemwingie to double his tally with a neat first-touch finish.
From then on Nigeria looked comfortable for much of the second period, largely containing Mozambique in midfield.
Fanuel Massinga was limited to unleashing a 40-yard free-kick that almost came off when it dipped sharply, but not enough to trouble Enyeama.
Mozambique had their best chance to get back into the game when Domingues twisted and turned his way into a position to cross for Dario Monteiro, whose fine header was well saved at close range by Enyeama.
But the game was put beyond reach when Mikel punished sloppy defending to shoot at Rafael, who parried it into the path of Martins who finished confidently to put Nigeria through.
Nigeria went back into their shells for a spell and allowed the Mozambicans to come onto the ball, before Odemwingie took charge and created the opener single-handedly.
The Lokomotiv Moscow man was gifted acres of space and time as he ran at the Mambas' defence and gratefully picked his spot to brilliantly fire in past the diving Rafael.
It was a deserved goal for a player who had been knocking on the door throughout the half.
Nigeria doubled their lead just after the break with a clinical break from their own half.
Yakubu was played onside on the left and squared for the on-rushing Odemwingie to double his tally with a neat first-touch finish.
From then on Nigeria looked comfortable for much of the second period, largely containing Mozambique in midfield.
Fanuel Massinga was limited to unleashing a 40-yard free-kick that almost came off when it dipped sharply, but not enough to trouble Enyeama.
Mozambique had their best chance to get back into the game when Domingues twisted and turned his way into a position to cross for Dario Monteiro, whose fine header was well saved at close range by Enyeama.
But the game was put beyond reach when Mikel punished sloppy defending to shoot at Rafael, who parried it into the path of Martins who finished confidently to put Nigeria through.
Story from BBC SPORT
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